James bond and Bruce both are very unique in their skill sets but Bruce with out his bat suite is only has to use his hands and bruce wyne himself trained in various martial arts
Comparison between bruce wayne and James bond
Bond has strong legendary fighting skills that he uses on land. He trains privately using a manual for unarmed combat titled “Stay Alive!” Bond is skilled in many areas of combat: karate, judo, jujitsu, tae kwon do, boxing, wrestling and being able to kill a man with a single blow five different ways. He can defend and kill without the use of a gun, but if he has to use his gun his aim is always right on target. He combines his combat skills with leisure sports which he learned during his teenage years such as skiing and snowboarding. Bond practises his sports seriously such as when he practices skiing at a high level of altitude in the mountains so he trains his body not to be fatigued. He combines sports and combat making it look fun but his fighting skills he develops by training keep him alive
See he is not a serious workout guy and he got good training in martial skills .he is more skilled in sky diving,sea related skills and land fighting skills using equipment and in many bond films we can see james bond struggling in one to one fights with out guns
in contrary bruce wayne is a heavy workout guy ,physically extremely fit and trained in one to one combat skills
Now from Wikipedia page of skills
Batman has trained extensively in various martial arts, mastering over 127 different types, making him one of the best hand-to-hand fighters in the DC Universe. Superman describes Batman as “the most dangerous man on Earth”, able to defeat an entire team of super powered extraterrestrials by himself in order to rescue his imprisoned teammates in Grant Morrison’s first storyline in JLA
So although the match will be interesting comparing to the 127 marital arts with his physical prowess bruce wayne will win the match